Product ID:01030, UNOCAL 76 AVIATION GASOLINE 1001130
MSDS Date:04/14/1989
FSC:9150
NIIN:00N017626
MSDS Number: BPGMZ

UNION OIL COMPANY OF CALIFORNIA

1201 W 5TH ST
LOS ANGELES, CA 90017
US

Emergency Phone: 800-356-3129;800-424-9300(CHEMTREC)

Info Phone: 213-977-7589

Cage: 5W523

UNION OIL COMPANY OF CALIFORNIA

7600 SCHAUMBURG, IL 60196 US

Telephone: 800-438-2968

Cage: 5W523

SIDE W/HEAD DOWN.IF POSS, DO NOT LEAVE VICTIM

RTECS: 9999999ZZ

(E.G.,IN CLSD SPACES/W/DELIB ABUSE)MAY BE ASSOC

RTECS: 9999999ZZ

DRUGS MAY INITIATE CARDIAC ARRHYTHMIAS IN PERSONS

RTECS: 9999999ZZ

POTENTIAL SHOULD BE CONSIDERED.IF SYMPATHOMIMETIC

RTECS: 9999999ZZ

HOT METAL SURF AWAY FROM RELS.STOP LEAK IF CAN

RTECS: 9999999ZZ

APPROP ABSORB.PVNT SPILL LIQ FROM ENTERING

RTECS: 9999999ZZ

FREE OF HOT METAL SURF & OTHER SOURCES OF IGNIT.

RTECS: 9999999ZZ

EXHST SYS MAY BE REQ.WHERE EXPLO MIXT MAY BE PRESENT,

RTECS: 9999999ZZ

BASED ON TESTS IN LAB ANIMALS.BENZENE IS KNOWN

RTECS: 9999999ZZ

IN THE GENETIC MATL (DNA) OF A CELL.

RTECS: 9999999ZZ

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

OSHA PEL 300 PPM;500 PPM STEL

ACGIH TLV: 300 PPM;500 PPM STEL

BENZENE

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 1-5%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

0.1 GM/GAL

Fraction By Weight: SEE ING

TOLUENE

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 1-15%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENE

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 1-21%

OSHA PEL 100 PPM;150 PPM STEL

ACGIH TLV: 100 PPM;150 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

HEXANE; (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

BENZENE, ETHYL-; (ETHYLBENZENE)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1-5%

OSHA PEL 100 PPM;125 PPM STEL

ACGIH TLV: 100 PPM;125 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHER, TERT-BUTYL METHYL; (METHYL TERT-BUTYL ETHER)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 0-11%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

BENZENE, 1,2,4-TRIMETHYL-; (1,2,4-TRIMETHYLBENZENE)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 1-5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM

PERSONS W/PRE-EXISTING HEART DISORDERS MAY BE

RTECS: 9999999ZZ

IF EXPOSED TO HIGH CONCENTRATIONS OF THIS MATERIAL.

RTECS: 9999999ZZ

CALL MD IMMED.IF VICTIM STOPS BRTHG,IMMED

RTECS: 9999999ZZ

BE ADMINISTERED BY QUALIFIED PERS.CALL MD

RTECS: 9999999ZZ

MOUTH BECAUSE THIS MATL CAN ENTER LUNGS & CAUSE

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYE:MAY CAUSE IRRIT. DIRECT CONT
W/LIQ/EXPOS TO VAPS/MISTS MAY CAUSE STINGING, TEARING & REDNESS.
SKIN:MAY CAUSE IRRIT. PRLNGD/RPTD CONT MAY CAUSE REDNESS, BURNING &
DRYING & CRACKING OF SKIN. CONT MA Y RESULT IN SKIN ABSORP BUT SYMP
OF TOXARE NOT ANTICIPATED BY THIS ROUTE ALONE UNDER NORMAL CNDTNS
OF (EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE: GROUP 1 (NTP, IARC). OSHA
REGULATED.
Effects of Overexposure:HLTH HAZ:USE. INHAL:WHILE MATL HAS A LOW DEGREE
OF TOX, BRTHG HIGH CONC OF VAPS/MISTS MAY CAUSE FLUSHING, BLURRED
VISION, NAUS & SIGNS OF NERV SYS DEPRESS (E.G., HDCH, DROWS, DIZZ,
LOSS OF CONSCIOUSNE SS, CONVULS, RESP COLLAPSE & DEATH.
INGEST:ASPIR HAZ - CAN ENTER LUNGS DURING SWALLOWING/VOMIT & CAUSE
LUNG (SUPP DATA)
Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN
DISORDERS MAY BE MORE SUSCEPTIBLE TO EFTS OF MATL. RESP SYMP ASSOC
W/PRE-EXISTING LUNG DISORDERS (E.G., ASTHMA-LIKE CNDTNS) MAY BE
AGGRAV BY EXPOS TO THIS MATL. (ING 10)

First Aid:EYE:MOVE VICTIM AWAY FROM EXPOS & INTO FRESH AIR.FLUSH
W/CLEAN WATER FOR AT LEAST 15 MIN.IF SYMP PERSISTS, CALL
MD.SKIN:WIPE MATL FROM SKIN & REMOVE CONTAM SHOES & CLTHG.CLEANSE
AFFECTED AREA(S) THORO BY WASHING W/MILD SOAP & WATER & IF NEC, A
WATERLESS SKIN CLEANSER.IF IRRIT/REDNESS DEVELOPS & PERSISTS, CALL
MD. INHAL:MOVE VICTIM AWAY FROM SOURCE OF EXPOS & INTO FRESH AIR.IF
SYMP PERSIST,(ING 12)

Flash Point Method:TCC
Flash Point:-45F,-43C
Extinguishing Media:THE USE OF DRY CHEMICAL, FOAM OR CO*2 IS
RECOMMENDED. WATER MAY BE INEFFECTIVE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER SPRAY MAY BE USEFUL IN MINIMIZING VAPS & COOLING CNTNRS
EXPSD TO HEAT & FLAME. AVOID (SUPP DATA)
Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE AND MAY BE IGNITED BY
HEAT, SPARKS, FLAME OR STATIC ELECTRICITY. IF CNTNR IS NOT PROPERLY
COOLED, IT MAY EXPLODE IN HEAT OF FIRE.(SUPP DATA)

Spill Release Procedures:STAY UPWIND & AWAY FROM SPILL.WEAR APPROP PROT
EQUIP INCL NIOSH/MSHA APPRVD RESP PROT.DO NOT ENTER/STAY IN AREA
UNLESS MONITORING INDICATES THAT IT IS SAFE TO DO SO.ISOLATE HAZ
AREA & RESTRICT ENTRY T O EMER CREW.KEEP ALL SOURCES OF IGNIT &(ING
19)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE ONLY IN APPRVD CNTNRS.KEEP
CNTNRS TIGHTLY CLSD,OUT OF DIRECT SUNLIGHT & AWAY FROM ALL SOURCES
OF IGNIT.KEEP AWAY FROM INCOMPAT MATLS.
Other Precautions:OUTDOOR/DETACHED STORAGE IS PREF.INDOOR STORAGE
SHOULD BE IN A STANDARD FLAM LIQ STORAGE ROOM.PROVIDE ADEQ VENT &
POST AREA "NO SMOKING/OPEN FLAME".BOND & GROUND ALL EQUIP WHEN
TRANSFERRING FROM ONE V ESSEL TO ANOTHER.KEEP WORK AREA (ING 21)

Respiratory Protection:NIOSH/MSHA APPRVD RESP PROT ADVISED WHEN CONC
EXCEED ESTABLISHED EXPOS LIMITS. DEPENDING ON AIRBORNE CONC, USE A
RESP/GAS MASK WITH APPROP CARTRIDGES & CANNISTERS OR SUPPLIED AIR
EQUIP.
Ventilation:IF CURRENT VENT PRACTICES ARE NOT ADEQ TO MAINTAIN AIRBORNE
CONC Protective Gloves:IMPERMEABLE.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:IT IS SUGGESTED THAT A SOURCE OF CLEAN WATER
BE AVAIL IN WORK AREA FOR FLUSHING EYES & SKIN. IMPERVIOUS CLOTHING
REC.
Work Hygienic Practices:AVOID INHAL OF VAPS & PERS CONT W/PROD. WASH
THOROUGHLY AFTER HANDLING. LAUNDER SATURATED CLTHG BEFORE WEARING.
Supplemental Safety and Health
FIRE FIGHT PROC:SPREADING BURNING LIQ W/WATER USED FOR COOLING
PURPOSES. MOVE UNDAMAGED CNTNRS FROM FIRE AREA IF CAN BE DONE W/O
RISK. EXPLO HAZ:FLASHBACK ALONG VAP TRAIL MAY OCCUR. EFTS OF
OVEREXP:IN FLAM & DMG. EXCESS QTYS MAY CAUSE IRRITOF DIGESTIVE
TRACT & SIGNS OF NERV SYS DEPRESS. GAS IS POSS CANCER HAZ (ING 23)

Boiling Pt:B.P. Text:>100F,>38C
Vapor Density:>1
Spec Gravity:0.70-0.72
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE = 1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:GREEN LIQUID WITH A GASOLINE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS SUCH AS CHLORINE, PERMANGANATES & DICHROMATES
MAY CAUSE FIRE OR EXPLOSION.
Stability Condition to Avoid:AVOID CONTACT OF LIQUID, FUMES, OR VAPORS
WITH ANY SOURCE OF HEAT, SPARKS, OR FLAME.
Hazardous Decomposition Products:COMBUST MAY YIELD SIGNIFICANT AMTS OF
CO & SMALL AMTS OF OXIDES OF SULFUR & NITROGEN, BENZENE & OTHER
ORGANIC CMPDS.

Waste Disposal Methods:DISPOSE OF PRODUCT IN ACCORDANCE WITH LOCAL,
COUNTY, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.